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Pool Care
Pool Water Chemistry Overview
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Pool Care and Legacy Pool
Information
Everything you wanted to know about Pool Water
Chemistry, and were afraid you would have to ask.
1. WHAT POOL CHEMICALS DO I NEED?
a. Chlorine either in the form of liquid, dry, or
stable dry.
b. Acid, either in the form of liquid (muriatic
acid), or dry (sodium bisulphate).
c. Algaecide, either in the form of liquid or dry
granular or tablet. (if chlorine and acid are used
properly, this product may not be necessary).
d. Soda ash, either in granular or block form (if
too much acid is used).
2. TYPES OF CHEMICALS
A. CHLORINE
1. Liquid Chlorine (SODIUM HYPOCHLORITE). This form
of chlorine is made in a concentrated from
especially for pool use. It contains between 10% and
16% available chlorine. Liquid chlorine may be
poured directly into the pool but it should be
distributed over as wide an area of the pool as is
practical. Avoid contact of liquid chlorine with
clothes and delicate tissue.
1. Dry Chlorine (CALCIUM HYPOCHLORITE) This type of
chlorine is available in either granular or tablet
forms. It usually contains 70% available chlorine.
The granular form dissolves readily while the
tablets usually take several hours. Calcium
hypochlorite contains an insoluble ingredient that
leaves a residue in the pool. The granular and
tablet form should be introduced in a floating
chlorine dispenser.
Dry Stable Chlorine (SODIUM OR POTASSIUM
DICHLORO-ISOCYANURATE OR TRICHLORO-S-TRIAZINE
TRIONE). This type of chlorine is available in both
granular and tablet form. Its principle advantage is
that it contains a stabilizing factor that holds the
chlorine for extended periods thus providing
prolonged disinfecting activity. No insoluble
residue is left when the material dissolves. Another
advantage is that there is little or no addition of
alkalinity to the water when this type of chlorine
is used as compared to sodium hypochlorite and
calcium hypochlorite.
B. ACID
1. Liquid Acid (MURIATIC). This product is quite
strong and must be handled and used with great care.
This material will burn skin, clothes and almost
anything it comes in contact with. KEEP THIS PRODUCT
AND ALL POOL CHEMICALS OUT OF THE REACH OF CHILDREN.
2. Dry Acid (SODIUM DISULPHATE). This product is
easier to store but it also must be used with care.
When mixed with water this product is an effective
pH reducer.
C. ALGAECIDES. There are some chemicals that have
been developed primarily to control and kill algae.
Since there are many different such compounds, it is
best when using them, to be guided by the
manufacturer’s instructions. Generally chlorine must
be used in conjunction with algaecides.
D. CHLORINE STABILIZER (CONDITIONER). The use of
this substance assists in the stabilization of
chlorine to permit longer periods of protection. If
stable chlorine is used as a regular source of
chlorine the conditioner need be added only once
with each filling of the pool. If other types of
chlorine are used, the stabilizer should be
replenished about every 3 to 4 weeks. See directions
on stabilizer container regarding the amount to use.
HOW MUCH CHLORINE IS REQUIRED? It is advisable to
follow the directions of the manufacturer for his
particular products. As a rule this will provide
dosages that will produce satisfactory results for
normal treatment. During the initial start up, it is
advisable to double the dosages shown for the first
few days.
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TYPE OF
CHLORINE
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POOL
CAPACITY IN GALLONS
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1,000
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2,500
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5,000
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7,500
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10,000
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12,500
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15,000
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Calcium
Hypochlorite Granular
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½ oz.
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1 oz.
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2 oz.
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3 oz.
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4 oz.
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5 oz.
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6 oz.
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Calcium
Hypochlorite Tablets
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3
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6
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12
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18
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24
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30
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36
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Sodium
Hypochlorite 15% Solution
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1-½ oz.
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4 oz.
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8 oz.
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12 oz.
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16 oz.
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20 oz.
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24 oz.
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Sodium or
Potassium dichloroisocyanurate or Trichloro-s-Triazinetrione*
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¼ oz.
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½ oz.
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1 oz.
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1- ½ oz.
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2 oz.
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2- ½ oz.
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3 oz
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* Due to stabilization action, test pool for
chlorine before adding. If chlorine is present in
water reduce dosage proportionately.
For effective control of bacteria and algae maintain
a chlorine residual of 0.3 to 0.6 ppm. If stabilized
chlorine is used, a residual of at least 1.0 ppm
should be maintained.
1. HOW MUCH STABLE CHLORINE IS REQUIRED? – The
stabilizing effect does not take place at one with
regular use of chlorinated cyanuric acid, unless a
conditioner is used with the initial treatment.
Without use of conditioner the dosage of stable
chlorine will have to be increased to double the
normal treatment for the first 3 or 4 weeks.
Afterwards, the average pool will require a dosage
of between 1 and 2 oz. per 10,000 gallons of water.
2. HOW IS THE POOL CONDITIONED TO ELIMINATE THE
STABILIZING WAITING PERIOD? – By adding 1 pound of
conditioner (cyanuric acid) to the pool for every
3000 gallons a residual stabilizing concentration of
40 ppm will be established. This will normally
achieve chlorine stabilization.
3. WHY DO I NEED TO USE ACID IN MY POOL? – The
addition of some chlorine raises the pH since liquid
(sodium hypochloride) tablet or granular (calcium
hypochloride) are basically alkaline, continued use
increases the pH above 7.6. to counteract this an
acid must be used. Sodium bisulphate or muriatic
acid will reduce the alkalinity.
4. HOW MUCH ADIC DO I USE? – There are acid demand
test kits available at your pool store that will
tell you exactly how much acid is required at any
one time. Be cautious when adding acid to prevent
contact with tissue or clothing. Never put more than
one pint of muriatic or 1 lb. of sodium bisulphate
into a pool at one time. Wait four (4) hours and
test pH before adding more acid.
1. WHY DO I NEED TO USE SODA ASH IN MY POOL? – The
pH at times may drop lower than 7.2 by adding too
much acid or from the presence of some foreign
material in the water. Use soda ash to raise pH to
safe level.
2. DO I ADD CHEMICALS TO MY FILTER? – NO! Pool
chemicals should not be added directly to filter or
surface skimmer. Diatomaceous earth is the only item
that should be added to skimmer of filter.
3. HOW DO I ADD CHEMICALS TO THE POOL? – A
predetermined amount should be selected and filter
should be running. Caution. Protect your eyes, skin
and clothing at all times. Do not mix different
chemicals. Do not add different chemicals to pool at
the same point.
A. Liquid Chlorine – pour slowly into the water by
walking around the pool. Place container as close to
water as possible to avoid splashing.
B. Dry Chlorine – Granular or Tablet – can be placed
in a floating chlorine dispenser. Do not pour any
un-dissolved powder into pool because this may cloud
water, shorten filter cycle, or settle to bottom and
stain the poor liner.
C. Dry Stable Chlorine – Granular, powder or tablet
should be placed in a floating dispenser
D. Muriatic Acid – Dilute acid 10 to 1 or 20 to 1
with water in a plastic bucket and slowly pour
solution into water while walking around pool.
A. Sodium Bisulphate – dissolve in a gallon of water
(use plastic bucket) and slowly pour diluted liquid
into water while walking around pool. Acid normally
will react and be completely neutralized in 30
minutes with good pool circulation.
B. Soda Ash – pre-dissolve soda ash in water and
slowly add solution to pool water.
12. WHEN IS THE BEST TIME FOR CHLORINATION? – In the
evening after the sun has gone down and the day’s
swimming is over. High temperatures and sunlight
tend to dissipate chlorine rapidly.
13. WHEN IS THE BEST TIME TO ADD ACID? – In the
morning, however, one should test the water for
chlorine residual and pH prior to the addition of
any chemicals.
14. WHEN SHOULD I TEST FOR CHLORINE RESIDUAL? – In
the morning, before swimmers into the pool. If the
bathing load has been heavy in the morning, an
afternoon test is suggested to be sure the water is
always properly chlorinated for healthful swimming.
15. HOW DO I TEST FOR CHLORINE? – By using your pool
test kit. This may either be in the form of single
chlorine test set or a duplex test kit in which you
can test for chlorine and pH. The chlorine test set,
either OTO or DPD indicates the concentration of
chlorine in the water by a simple color change of
pool water sample which is compared to standard
color codes. To be sure of the chlorine residual
this test should be made daily.
16. WHAT IS SUPERCLORINATION? – (SHOCK TREATMENT) –
Continued low concentrations of chlorine tend to
permit strains of organisms to develop which are
more resistant to the normal concentration of
chlorine. Because of this it is advisable to apply
shock treatment, or superchlorination treatment, to
control these organisms and also to burn out other
accumulation of organic matter. This type of
treatment calls for from five to ten times the
normal dosage of chlorine once every two or three
weeks.
17. COMBINED CHLORINE – Common Problem – When
chlorine becomes combined there are some indications
which often appear:
1. A Strong test of chlorine (this is a reading of
chlorine in an unusable from).
2. A strong odor of chlorine (not found when
chlorine and pH are in balance).
3. Swimmers complain of eye irritation (this is not
a normal reaction of a bather to chlorine).
4. Water tends to be cloudy or grayish.
To correct this condition (and almost all normal
problems) one should:
ADJUST pH (so that chlorine is available to perform
its three (3) basic functions: to kill bacteria – to
kill algae – to destroy organic matter in the
water).
SUPER-CHLORINATE OR SHOCK. With the adjusted pH,
this super-chlorinization will drive off the
unusable forms of chlorine which cannot be restored,
and replace them with usable forms of chlorine (in a
proper pH condition) which is now available to
perform the three (3) basic functions which chlorine
is intended to perform: to kill bacteria – to kill
algae – to destroy organic matter.
Again, it is good practice to super-chlorinate once
every two or three weeks.

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